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						<h4>2nd European Chemistry Conference 2019</h4>
						<h6 class="procvenue">May 15-16, 2019 at Amsterdam, Netherlands, Amsterdam, Netherlands</h6>
						<h6 class="procvenue">Keynote Session Abstracts</h6>
						<h6 class="procvenue">DOI: <a href="http://dx.doi.org/10.18689/2640-5180.a1.001">10.18689/2640-5180.a1.001</a></h6>
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									<h4 class="proc-title">Catalysis of Organic Reactions in Binary Solvent Mixtures</h4>
									<p class="proc-author">Wojciech J. Kinart</p>
									<p class="proc-affl">University of Lodz, Poland</p>
									<p><a href="https://madridge.org/journal-of-cancer-study-and-research/cancer-science-2019-keynote-proceedings/2640-5180.a4.001-k001.pdf" class="btn btn-danger pull-right" target="_blank">Download PDF</a></p>
									<p class="proc-para"><span class="firstletter_para">W</span>e have studied the catalysis of organic reactions in binary solvent mixtures and concentrated solutions of inorganic salts. These reactions include: metalloene reactions of aldehydes, ketones and tin phenoxides, hydrostannylation of alkenes and free radical additions leading to formation of new carbon-carbon bonds. We have been interested in explanation of the catalytic effect of different lithium salts on studied reactions. We have attributed it to the large “internal pressure” of the solvent, increase of its polarity and viscosity, Lewis acidity and facilitation of formation of the transition state.</p>
									<p class="proc-biog"><b>Biography:</b><br/>Dr. Wojciech J. Kinart was born on the 17th of May 1953 in Łódź. He graduated from the University of Łódź in 1977. On the 17th of April, 1980, he was awarded the Ph.D Degree in Chemistry. In 1996 he was awarded the habilitation degree in Chemistry at the University of Łódź. He is the author of 120 papers, two chapters in Comprehensive Heterocyclic Chemistry III, Oxford, 2008; and one chapter in Tin Chemistry: Fundamentals, Frontiers and Applications, Wiley, 2008. Research areas of his interest include: organometallic chemistry, organic and organometallic peroxides, ene reaction and metalloene reaction, physicochemical studies of equilibria in liquid solvent mixtures.</p>
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									<h4 class="proc-title">Carbolong Chemistry: A Novel π-Conjugated System</h4>
									<p class="proc-author">Haiping Xia</p>
									<p class="proc-affl">Xiamen University, China</p>
									<p class="proc-para"><span class="firstletter_para">T</span>he formation of metal-carbon bonds is a fundamental principle in organometallic chemistry. Construction of organometallics with more than two metal-carbon  bonds remains a great challenge. Recently, we reported a novel organometallic complex, metallapentalyne, containing three metal-carbon  bonds in the equatorial plane. X-ray study reveals that the carbyne angle is only 129.5°, which is the smallest carbyne angles observed thus far. Theoretical study shows that it is the first example of planar Möbius aromatic species. Metallapentalyne formally consists of a seven-atoms carbon chain and a transition metal (M+7C). Thereafter, with the extension of this carbon chain (ranging from seven atoms to twelve atoms), a series carbon-based polydentate organometallics (M+8C to M+12C) chelates containing four or five metal-carbon bonds were synthesized. For all of these complexes, the binding atoms, even the backbones are carbon atoms. These carbon-based polydentate chelates are named as “carbolong complexes”. A number of exceptional organometallic complexes elineated in this work. For example, M+8C represents the first example of -aromaticity in an unsaturated three-membered ring; M+10C is the first metal-bridged tricyclic aromatic system, in which the metal center is shared by three aromatic five-membered rings; M+12C represents the upper limit of coordination number of a metal atom bonding with carbon ligands in a planar geometry.</p>
									<p class="proc-para">In general, organometallic complexes are highly sensitive towards air, water and heat. However, these new metallacycles exhibit remarkable stability, which can even be stable at 100o C in air. Unique properties, such as aggregation induced emission enhancement, large stokes shifts and long lifetime (Nat. Chem. 2013, 5, 698) broad absorption from the ultraviolet-visible to the near-infrared
									region (Angew. Chem. Int. Ed. 2015, 54, 6181) and excellent photoacoustic and photothermal properties (Sci. Adv. 2016, 2, e1601031)
									have been demonstrated. Application of these carbonlong complexes on biomedicine and solar energy utilization is in progress in
									our laboratory.</p>
									<p class="proc-biog"><b>Biography:</b><br/>Dr. Haiping Xia was worked in Department of Chemistry, Xiamen University from 1999–2018. He has been Chair, Professor in Department of Chemistry, Southern University of Science and Technology from 2018-Present.</p>
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									<h4 class="proc-title">Carbolong Chemistry: A Novel π-Conjugated System</h4>
									<p class="proc-author">Haiping Xia</p>
									<p class="proc-affl">Xiamen University, China</p>
									<p class="proc-para"><span class="firstletter_para">T</span>he formation of metal-carbon bonds is a fundamental principle in organometallic chemistry. Construction of organometallics with more than two metal-carbon  bonds remains a great challenge. Recently, we reported a novel organometallic complex, metallapentalyne, containing three metal-carbon  bonds in the equatorial plane. X-ray study reveals that the carbyne angle is only 129.5°, which is the smallest carbyne angles observed thus far. Theoretical study shows that it is the first example of planar Möbius aromatic species. Metallapentalyne formally consists of a seven-atoms carbon chain and a transition metal (M+7C). Thereafter, with the extension of this carbon chain (ranging from seven atoms to twelve atoms), a series carbon-based polydentate organometallics (M+8C to M+12C) chelates containing four or five metal-carbon bonds were synthesized. For all of these complexes, the binding atoms, even the backbones are carbon atoms. These carbon-based polydentate chelates are named as “carbolong complexes”. A number of exceptional organometallic complexes elineated in this work. For example, M+8C represents the first example of -aromaticity in an unsaturated three-membered ring; M+10C is the first metal-bridged tricyclic aromatic system, in which the metal center is shared by three aromatic five-membered rings; M+12C represents the upper limit of coordination number of a metal atom bonding with carbon ligands in a planar geometry.</p>
									<p class="proc-para">In general, organometallic complexes are highly sensitive towards air, water and heat. However, these new metallacycles exhibit remarkable stability, which can even be stable at 100o C in air. Unique properties, such as aggregation induced emission enhancement, large stokes shifts and long lifetime (Nat. Chem. 2013, 5, 698) broad absorption from the ultraviolet-visible to the near-infrared
									region (Angew. Chem. Int. Ed. 2015, 54, 6181) and excellent photoacoustic and photothermal properties (Sci. Adv. 2016, 2, e1601031)
									have been demonstrated. Application of these carbonlong complexes on biomedicine and solar energy utilization is in progress in
									our laboratory.</p>
									<p class="proc-biog"><b>Biography:</b><br/>Dr. Haiping Xia was worked in Department of Chemistry, Xiamen University from 1999–2018. He has been Chair, Professor in Department of Chemistry, Southern University of Science and Technology from 2018-Present.</p>
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								<div class="procdetails clearfix">
									<h4 class="proc-title">Carbolong Chemistry: A Novel π-Conjugated System</h4>
									<p class="proc-author">Haiping Xia</p>
									<p class="proc-affl">Xiamen University, China</p>
									<p class="proc-para"><span class="firstletter_para">T</span>he formation of metal-carbon bonds is a fundamental principle in organometallic chemistry. Construction of organometallics with more than two metal-carbon  bonds remains a great challenge. Recently, we reported a novel organometallic complex, metallapentalyne, containing three metal-carbon  bonds in the equatorial plane. X-ray study reveals that the carbyne angle is only 129.5°, which is the smallest carbyne angles observed thus far. Theoretical study shows that it is the first example of planar Möbius aromatic species. Metallapentalyne formally consists of a seven-atoms carbon chain and a transition metal (M+7C). Thereafter, with the extension of this carbon chain (ranging from seven atoms to twelve atoms), a series carbon-based polydentate organometallics (M+8C to M+12C) chelates containing four or five metal-carbon bonds were synthesized. For all of these complexes, the binding atoms, even the backbones are carbon atoms. These carbon-based polydentate chelates are named as “carbolong complexes”. A number of exceptional organometallic complexes elineated in this work. For example, M+8C represents the first example of -aromaticity in an unsaturated three-membered ring; M+10C is the first metal-bridged tricyclic aromatic system, in which the metal center is shared by three aromatic five-membered rings; M+12C represents the upper limit of coordination number of a metal atom bonding with carbon ligands in a planar geometry.</p>
									<p class="proc-para">In general, organometallic complexes are highly sensitive towards air, water and heat. However, these new metallacycles exhibit remarkable stability, which can even be stable at 100o C in air. Unique properties, such as aggregation induced emission enhancement, large stokes shifts and long lifetime (Nat. Chem. 2013, 5, 698) broad absorption from the ultraviolet-visible to the near-infrared
									region (Angew. Chem. Int. Ed. 2015, 54, 6181) and excellent photoacoustic and photothermal properties (Sci. Adv. 2016, 2, e1601031)
									have been demonstrated. Application of these carbonlong complexes on biomedicine and solar energy utilization is in progress in
									our laboratory.</p>
									<p class="proc-biog"><b>Biography:</b><br/>Dr. Haiping Xia was worked in Department of Chemistry, Xiamen University from 1999–2018. He has been Chair, Professor in Department of Chemistry, Southern University of Science and Technology from 2018-Present.</p>
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						<h3 class="s-property-title">Abstracts</h3>
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							<li class="nav-item"><a class="nav-link active" href="#k001" data-toggle="tooltip" data-placement="bottom" title="‘Smart’ Drug Delivery Systems for the Treatment of Cancer">A1: ‘Smart’ Drug Delivery Systems for the Treatment of Cancer</a></li>
							<li class="nav-item"><a class="nav-link" href="#k002" data-toggle="tooltip" data-placement="bottom" title="4 New Methods of Non-Invasive Early Diagnosis of Various Cancer Including Detection of Cancer from ECG & Individualized Safe Effective Treatment of Hopelessly Advanced Cancer Patients with Metastases using 3 Combination of 1) Combined Optimal Doses of Vitamin D3 with 10 Unique Beneficial Effects & Dragon Fruit Containing DHEA, Zinc, Magnesium, Lithium, etc. 2) Selective Drug Uptake Enhancement Method 3) Stimulation of Thymus Gland Representation Area of the Back of Each Hand with Increased Thymosin Α1 & Thymosin Β4">A2: 4 New Methods of Non-Invasive Early Diagnosis of Various Cancer Including Detection of Cancer from ECG & Individualized Safe Effective Treatment of Hopelessly Advanced Cancer Patients with Metastases using 3 Combination of 1) Combined Optimal Doses of Vitamin D3 with 10 Unique Beneficial Effects & Dragon Fruit Containing DHEA, Zinc, Magnesium, Lithium, etc. 2) Selective Drug Uptake Enhancement Method 3) Stimulation of Thymus Gland Representation Area of the Back of Each Hand with Increased Thymosin Α1 & Thymosin Β4</a></li>
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